Applied Science and Convergence Technology 2020; 29(6): 162-166
Published online November 30, 2020
https://doi.org/10.5757/ASCT.2020.29.6.162
Copyright © The Korean Vacuum Society.
Yejin Shon^{a}, Sora Lee^{a}, Dong-gil Kim^{a}, Deuk-Chul Kwon^{b}, and HeeHwan Choe^{a,*}
^{a}School of Electronics and Information Engineering, Korea Aerospace University, Goyang 10540, Republic of Korea
^{b}Plasma Technology Research Center, National Fusion Research Institute, Gunsan 54004, Republic of Korea
Correspondence to:E-mail: choehh@kau.ac.kr
Pulsed inductively coupled plasma (ICP) is widely used owing to its advantages of increasing plasma uniformity and reducing charge-induced damage in low-temperature semiconductor processing. In this research, the plasma parameters of pulsed plasma were investigated via fluid-based simulation, assuming a two-dimensional axisymmetric structure of the ICP equipment used in semiconductor processing. To improve the simulation accuracy, the capacitive electric field was considered along with an inductive electric field. In addition, the simulation was conducted under Druyvesteyn electron energy distribution function (EEDF) conditions, as the EEDFs of ICP tend to be non-Maxwellian. Results obtained in this study were compared with the experimental values to prove the simulation validity.
Keywords: Plasma simulation, 2D axisymmetric inductively coupled plasma, Druyvesteyn Electron energy distribution function, Pulsed plasma
Inductively coupled plasma (ICP) discharge is widely used in semiconductor manufacturing processes [1–2]. Due to the advantage of increasing plasma uniformity and reducing charge-induced damage, pulsed ICP is used instead of continuous wave (CW) plasma [3–5]. As pulse power with a specific pulse frequency and duty cycle is applied to the antenna, the high ion energy is generated in the pulse-on state (high-state) and used for etching. In the off state (zero-state), the density of the electron and cations decrease as the plasma sheath disappears. In Ref. [6], Han et al. measured key plasma parameters, such as electron density, electron temperature, and electron energy distribution function (EEDF), in pulsed argon ICP used in industrial etching processes through different probes.
EEDF is required for the calculation of reaction coefficients for electron collision reactions, while ionization and excitation processes are greatly influenced by EEDF. Therefore, the plasma calculation results vary, based on which EEDF is considered. Maxwellian assumes that electrons are in thermal equilibrium and used under a high ionization degree. However, because this study has a low degree of ionization, Druyvesteyn may produce more appropriate results [7].
In plasma simulation based on a fluid model, the drift-diffusion approximation is commonly used in the momentum equations to reduce the computational resources. Some terms in the momentum equations are neglected by assuming that the electron motion is dominated by the collision and in a steady-state [8]. This approximation is suitable for use under certain conditions: collisional plasma, gas pressure over 10 mTorr, and very low ionization degree [7]. Because the process conditions in this study are suitable for using the approximate equation, the drift-diffusion approximation is applied to the momentum equation of electron density and electron energy density.
This study was carried out based on the information presented in the experimental paper [6], with the same process conditions used in the simulation model, assuming a two-dimensional (2D) axisymmetric structure. In the simulation, cases were appropriately partitioned for each probe used in the measurement, and all cases were performed with Druyvesteyn EEDF because the EEDF of ICP is often non- Maxwellian. To obtain results close to the experiment, heat transfer and gas flow effects are considered, as shown in Fig. 1.
This paper is organized into 4 sections: 1) Introduction for the background and brief overview; 2) Model description, including the overall scheme, and explanations for the equations; 3) Results and discussion of comparing the simulation results with experimental measurements to validate the study; 4) Conclusion for the result analysis and discussion of future work.
For comparison, the model is constructed almost similar to the equipment used in the experimental paper, whose structural diagram is shown in Fig. 2. Although the experimental equipment is three-dimensional, a 2D axisymmetric model is assumed to reduce com- putational resources.
The pre-rotation structure in Fig. 2(b) is demonstrated in Fig. 3. There are six plasma chamber areas: antenna, air cap, ceramic window, wafer, chuck, and plasma region. The antenna is made of copper with a three-turn coil with a 3 mm radius and is surrounded by an air cap that divides the area from the outside. Pulsed power was applied with the following conditions: duty cycle 50 %, pulse frequency 1 kHz, driving frequency 2 MHz, and current 24 A for the peak power of 300 W. Below it is a ceramic window composed of Al_{2}O_{3}, which separates the antenna from the plasma region and allows the transmission of electromagnetic waves to the plasma region [9]. In the plasma region, Ar gas was injected into the inlet under the conditions of 100 sccm and 25 mTorr, with an outlet at the chamber bottom. Although it does not participate in the calculation, a chuck and a 300-mm wafer were constructed under the plasma region to aid visual understanding. Additionally, the collision processes in the Ar discharge are summarized in Table I.
Table 1 . Important collision processes in the argon discharge.
Reaction | Formula | Type | ∆ε (eV) | Ref. |
---|---|---|---|---|
1 | Elastic | 0 | [10] | |
2 | Excitation | 11.5 | [10] | |
3 | Superelastic | −11.5 | [10] | |
4 | Ionization | 15.8 | [10] | |
5 | Ionization | 4.24 | [10] | |
6 | Penning ionization | - | [10] | |
7 | Metastable quenching | - | [10] |
This research is based on a fluid model and carried out with COMSOL Multiphysics 5.5.
When the AC current is driven to the antenna, a time-varying magnetic field is created in the rz direction. From this, the induced electric field is created in a vertical (θ) direction, transferring the energy that can cause collisions inside the chamber. Eqs. (1) to (3) enumerate the calculation formulas for these electromagnetic fields. Both the capacitive and inductive fields are considered when calculating the electric field, as indicated by Eq. (3).
where
The electrons that obtain energy from the induced electric field generate plasma through the collisions, as shown in Table I. The electron density is defined by the drift-diffusion approximation, as shown in Eq. (5).
The electron energy density is defined by Eq. (6) and follows the drift-diffusion approximation.
where
The generalized electron energy distribution function is shown in Eq. (9), and the definition of the variable used in the equation is shown in Eqs. (10) and (11): Depending on whether the number of ‘g’ is 1 or 2, it turns out to be Maxwellian EEDF and Druyvesteyn EEDF, respectively.
where
Heavy species transport properties are calculated according to the mixture-averaged diffusion model, as given in Eqs. (12)–(14).
where ρ is the density of the mixture, w is the mass fraction of the species,
The velocity and pressure fields are calculated based on the Navier–Stokes equations, where Eqs. (15) and (16) represent the momentum and mass conservation, respectively. Eq. (16) shows that the motion of the fluid follows the continuity equation.
where ρ is the gas density,
Considering heat transfer effects means that the convection of energy, thermal conduction, radiation, and a heat source are calculated as shown in Eq. (17) to control the internal energy over time and finally conserve energy.
where
In this section, simulations were performed under continuous wave conditions to determine the effects of EEDF and additional physics. Figure 4 illustrates the distribution of normalized plasma parameters, representing the maximum values for each by the numbers.
First, based on the difference in EEDF, it can be observed that the results considering Druyvesteyn EEDF have relatively lower electron density values, higher electron temperatures, and electric potential values than those of the Maxwellian EEDF. The Maxwellian EEDF exhibits a high maximum electron density by overestimating the ionization rate, and Druyvesteyn assumes that elastic collisions occur more frequently than inelastic collisions, which explains the above differences. When comparing the simulation results, the degree of ionization of Maxwellian EEDF was approximately 4.7 times higher than that of Druyvesteyn EEDF. Looking at the reaction rate of Druyvesteryn EEDF, elastic collisions showed 496 times higher than the excitation reaction and 781 times higher than the ionization reaction.
Next, the changes due to the effects of additional physics are compared. In Fig. 5, there are fluctuations in pressure and temperature, which are fixed as constant when not considering the effects of gas flow and heat transfer. As temperature increases, the electron density decreases according to the ideal gas law. Because the velocity and pressure fields are calculated by applying the gas flow effect, the pressure has the highest value at the inflow part, and the movement of fluid from inlet to outlet is considered as shown in a streamline.
This section compares the simulation results and plasma parameters measured using the double-sided planar Langmuir probe from Ref. [6]. The effects of gas flow and heat transfer were merged to create conditions similar to the actual process. The analysis of the results was performed in one pulse period, and the plasma parameters are observed at the center of the chamber(
Overall, for all three parameters, the trends of increasing or decreasing with the pulse-on and - off states are similar, but there exist slight numerical differences. This is because the simulation was conducted with Druyvesteyn EEDF, rather than the Boltzmann EEDF. The Boltzmann EEDF can calculate the drift velocity, a significant parameter in plasma reactions, and achieve maximum consistency in the kinetic and fluid description of electron dynamics [7]. Despite these advantages owing to the fatal drawback of the Boltzmann EEDF being computationally expensive, Druyvesteyn EEDF was used in this simulation to save computational resources.
Fundamental plasma parameters according to pulse-on and -off states were compared under the same conditions. The characteristics of the pulsed plasma in the off state are clearly illustrated in Fig. 7. The plasma sheath, which has a relatively large number of positive ions and neutrons than electrons, disappears as the power turned off. Therefore, a very low numerical value can be observed as the electrons are cooled. In addition, the density of electrons and cations decrease, which is a great feature of the pulse-off state. To more effectively observe the density decrease, a comparison according to the r direction at the center of the plasma region is shown in Fig. 8.
Section 3.3 is prepared for comparison with the Hairpin resonator probe results in Ref [6], which is affected by the presence of a plasma sheath near the tip [6]. As shown in Fig. 4, not considering the heat transfer and gas flow effects results in a wider sheath. Since the actual measurements were affected by the sheath, additional effects were not considered. The time-varying electron density in one pulse cycle is presented in Fig. 9. Figure 9(a) is a graph obtained by comparing the normalized simulation result with the experimental value, while the solid and dotted lines represent the simulated and measured values with the hairpin probe, respectively. As mentioned in section 3.2, the numerical value is not exactly suitable because the Boltzmann EEDF is not considered, but the trend along the r direction is similar. Figure 9(b) is a graph showing only the simulation results. One of the noticeable results in the experiment, it can be seen through simulation that the lowest profile does not appear at the start of discharge.
Additionally, conditions for obtaining valid plasma simulation results were studied. In the plasma region, the electron density along the
This study presented a simulation based on an experimental paper that measures the plasma parameters of pulsed ICP in a 300-mm wafer size chamber used in a semiconductor etching process. To reduce computational resources, a 2D axisymmetric structure was assumed and performed based on a fluid model. Because the electron energy distribution functions in ICPs are frequently Non-Maxwellian, Druyvesteyn EEDF was considered. The calculation accuracy is improved in calculating the electromagnetic field by considering not only the induced electric field but also the capacitive one. The gas flow effects account for changes in pressure and velocity fields, and the heat transfer physics for considering changes in enthalpy due to collision were merged. Appropriate physics settings were applied to each of the Langmuir and hairpin probes used in the experiment, and the simulation was validated through a comparison of the results. As the Boltzmann EEDF was not considered, which can obtain relatively more accurate electron transport properties than the Druyvesteyn EEDF, there were some numerical differences, but the profiles of the plasma parameters were similar. In addition, the characteristics of the pulsed plasma in the off state were examined. As the power is turned off, the sheath disappears, electrons cool down, and densities of electrons and cations decrease. In pulsed ICP simulation, it is necessary to observe after the 2^{nd} cycle to obtain accurate results.
To obtain more suitable plasma properties, the Boltzmann EEDF calculated using the two-term Boltzmann equation should be considered. Moreover, by applying the RF bias for capacitively coupled ICP, uniformity can be improved by controlling the ion collision energy at the substrate independently of the plasma density. Moreover, the etch rate and profile could be predicted through the ion energy and angular distribution functions according to the RF bias.
This work was supported by the National Research Council of Science & Technology (NST) grant by the Korean government (MSIP) (No. CAP-20-02-NFRI). And we would like to express our gratitude and appreciation to the Altsoft for supporting this work.