Applied Science and Convergence Technology 2020; 29(1): 10-13
Published online January 31, 2020
Copyright © The Korean Vacuum Society.
Mo Geun Soa , # , Hyun Jun Job , # , Gyoung Du Parkb , Jae-Jin Shimc , Woo Kyoung Kimc , Yeongho Kimd , Sang Jun Leed , and Jong Su Kimb , *
aAdvanced Photonics Research Institute, Gwangju Institute of Science and Technology, Gwangju 61005, Republic of Korea
bDepartment of Physics, Yeungnam University, Gyeongsan 38541, Republic of Korea
cSchool of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea
dKorea Research Institute of Standards and Science, Daejeon 34113, Republic of Korea
#Contributed equally to this work as first author.
This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-CommercialLicense (http://creativecommons.org/licenses/by-nc/3.0) which permits unrestricted non-commercial use, distribution,and reproduction in any medium, provided the original work is properly cited.
We have investigated the optical and electrical properties of flexible GaAs solar cells (SCs) fabricated by the epitaxial lift-off process using photoreflectance (PR) spectroscopy. The as-grown GaAs solar cells were transferred on Au/polyimide (ELA) and polydimethylsiloxane (PDMS; ELP) flexible substrates. In the PR spectra, low energy interference oscillations by internal multi-reflection were observed below the GaAs transition signals. The internal electric fields (
Keywords: GaAs, Solar cell, Epitaxial lift-off, Defects
GaAs is a direct transition semiconductor with high light absorption characteristics and theoretically has a band gap energy (1.42 eV) near 1.40 eV that can maximize the efficiency of solar cells (SCs). The efficiencies of GaAs SCs have been reported to be up to 29.1 % in single junction structures . In order to increase the efficiency of SCs by increasing the short-circuit current (JSC), methods of extending the absorption wavelength range or increasing the number of photo-generating carriers have been used. For this purpose, approaches such as preparing surface anti-reflective coatings using nanostructures, controlling the thickness of the absorption layer using light-trapping, and introducing quantum dots into the active layer have been used [2-5]. In addition, multi-junction SCs have been introduced to increase the open-circuit voltage (VOC). One of the fabrication methods for the multi-junction structure is wafer bonding using the epitaxial lift-off (ELO) method . The ELO technology is also widely used in flexible SCs for fabricating lightweight and wearable devices [6-10]. A general ELO method is to separate an epilayer and a substrate by wet-etching a sample on which thin film growth is completed, and transfer or bond the separated epilayer to a desired substrate [10,11]. The SC devices fabricated through the ELO method have the advantage of reducing the cost of SC fabrication because the substrate can be reused.
High quality GaAs SCs fabricated through ELO using an AlAs sacrificial layer and wet-etching with HF solution have been reported [11,12]. Many studies have investigated how the device characteristics are affected by the temperature and concentration of the etching solution in the wet-etching process [8,9]. However, research on the effects of defects generated during the ELO process on the efficiency and internal electric field of SCs is still insufficient.
In this study, the optical properties of a sample transferred to a polydimethylsiloxane (PDMS) substrate using ELO-processing (ELO-layer/PDMS; ELP) and a sample bonded to an Au/polyimide layer (ELO-layer/Au/polyimide; ELA) were investigated using excitation intensity (Iex) and temperature-dependent photoreflectance (PR). The defects generated during the ELO process were studied by comparing the photoluminescence (PL) measurement results for ELP and ELA.
The n+-n-p+ GaAs SCs were grown on a GaAs substrate using molecular beam epitaxy for the ELO process. In order to proceed with the ELO process, the GaAs (150 nm)/AlAs (15 nm)/GaAs (150 nm)/InGaP (50 nm) structures were grown on the n+-GaAs substrate. At this time, the AlAs sacrificial layer was used as an etching layer to separate the epilayer and substrate through wet-etching. The InGaP layer was used as an etch stop layer through a chemical mechanical polishing (CMP) process. Figures 1(a) and 1(b) show the ELA and ELP SC structures after the ELO process. After the ELO process, the ELA and ELP SCs exhibited p+-n-n+ structures. The reference GaAs (Ref) SC was grown on a GaAs substrate; the resultant SC exhibited a p+-n-n+ structure. In the ELA sample, Au was deposited on the polyimide thin film and sample on which growth was completed, and then Au-to-Au bonding was performed. The AlAs sacrificial layer was etched by dipping the sample into HF solution and the epilayer and substrate were separated. ELA was fabricated by etching the GaAs and InGaP layers through CMP. In the ELO process of the ELP SC, the AlAs sacrificial layer was etched by immersing the grown sample in HF solution to separate the epilayer and substrate, and the separated epilayer was transferred onto a PDMS/glass substrate. After that, GaAs and InGaP layers were etched as the last step of the ELA process. The detailed procedure is described in the previous study . A SC device was fabricated to study the effects of defects generated during the ELO process on solar cell efficiency. In order to investigate the defects in ELP and ELA SCs, PL experiments were performed at 300 K. A He-Ne (633 nm) laser was used as the excitation light source in PL and PR measurements.
(Color online) Schematic structure of (a) ELA and (b) ELP SCs.
In a previous study, we reported the excitation- and temperature-dependent PL results of the Ref, ELA, and ELP SCs . In the PL spectra at 300 K, strong emission signals due to the band-to-band transition in GaAs were observed around 1.425 eV. The signals with multiple peaks which were not observed in the Ref SC were observed at an energy lower than the GaAs signal in the ELA and ELP SCs. Therefore, these signals are assigned to the defect states generated during the ELO process . Additional peaks were produced by the interference effect of internal multi-reflection (IMR) . Defect states can affect the internal electric field (
Figure 2 shows the PR spectra of Ref, ELA, and ELP SCs at 300 K and the excitation intensity was 156 mW/cm2. In the PR spectra of the Ref, ELA, and ELP SCs, GaAs transition signals were observed around 1.425 eV and the Franz-Keldysh oscillations (FKOs) due to the
(Color online) PR spectra of Ref, ELA, and ELP SCs at 300 K.
Figure 3 shows the PR spectra of the Ref, ELA, and ELP SCs as a function of excitation intensity at 300 K. With increasing excitation intensity, all SCs exhibited an increasing amplitude and decreasing period. The increase in amplitude was due to the increase in modulation effects as more photo-generated carriers were generated by higher excitation laser intensity. A decrease in the FKO period indicated that the strength of
(Color online) PR spectra of (a) Ref, (b) ELA, and (c) ELP SCs as a function of excitation intensity at 300 K.
Figure 4 shows the
(Color online) Internal electric fields of Ref, ELA, and ELP SCs as functions of excitation intensity at 300 K.
In this study, the defect effects generated in the GaAs SCs through the ELO process were investigated by PR spectroscopy. In the process of separating the epilayer and GaAs substrate in the ELO process, defects occurred due to the stresses that deform thin film SCs. At 156 mW/cm2, the
This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education under grant numbers NRF-2017R1A6A3A11028070 and NRF-2018R1D1A3B07050824. This work was supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) and Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (No. 20163030013380). This study was partially supported by the Priority Research Centers Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2014R1A6A1031189).